Chemicals which present special hazards after prolonged storage

Some chemicals may gradually decompose during storage.  The release of decomposition by-products and consequently, the pressure buildup inside the container may cause a serious explosion.

Take formic acid as an example, prolonged storage of 98 - 100% formic acid may lead to the rupture of glass container due to the gradual decomposition of formic acid into carbon monoxide and water. 

 

List of Chemicals which are susceptible to internal pressure buildup during storage

Aluminum chloride Lithium Aluminum Hydride Ammonia solution
Benzenesulphonyl chloride Calcium carbide Calcium hydride
Calcium hypochlorite Chromic acid Cumeme hydroperoxide
Formic acid  Hydrogen peroxide Lauroyl peroxide
Lithium hydride Silicon tetrachloride Sodium borohydride
Sodium dithionite Sodium hydride Sodium hydrosulphite
Sodium hypochlorite Sodium peroxide Thionyl chloride
Urea peroxide